Polymer of intrinsic microporosity
WebWe report an ultrapermeable polymer of intrinsic microporosity (PIM-TMN-Trip) that is substantially more selective than PTMSP. From molecular … WebInvestigation of gas transport and other physical properties in relation to the bromination degree of polymers of intrinsic microporosity . × Close Log In. Log in with Facebook Log in with Google. or. Email. Password. Remember me on this computer. or reset password. Enter the email address you signed up with and we'll email you a ...
Polymer of intrinsic microporosity
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WebMolecular dynamics techniques have been used to investigate the pronounced permeability and selectivity of polymers of intrinsic microporosity (PIM). While helium exhibited greater permeability coefficients due to higher diffusivity resulting from its small molecular size, the higher permeability coefficients of carbon dioxide
WebThe resulting polymer was structurally characterized and proven permanently porous with a surface area of 305 m2 g−1. The high concentration of amines (–NH– and –NH2) within the backbone of the polymer result in exceptional selectivity (141) for CO2 over N2 and dynamic capacity (15.1 cm3 g−1) in the presence of water (20 : 80 v/v CO2 : N2, 91% relative … WebA polymer of intrinsic microporosity (PIM-1) containing nitrile groups was reacted by [2 + 3] cycloaddition reaction to give a polymer substituted with tetrazole groups (TZ-PIM), and then was further methylated to give a new PIM substituted with methyl tetrazole groups (MTZ-PIM). In contrast to TZ-PIMs, the MTZ-PIMs had distinctly improved solubility …
Webframeworks, graphene, membranes, imprinted polymers, polymers of intrinsic microporosity, nanoparticles, and nanofilms, to name a few. Topics discussed include … WebI am involved in organic synthesis, monomer & polymer design, the preparation and characterisation of novel Polymers of Intrinsic Microporosity (PIMs) both within the …
WebAging of polymers of intrinsic microporosity tracked by methanol vapour permeation Author links open overlay panel Kryštof Pilnáček a , Ondřej Vopička a , Marek Lanč a , Marcela Dendisová a , Miroslav Zgažar b , Peter M. Budd c , Mariolino Carta d , Richard Malpass-Evans d , Neil B. McKeown d , Karel Friess a
WebPolymers of intrinsic microporosity (PIMs) are a new type of polymer material with unique microporous structure and have been widely applied in gas separation. In recent years, … literary gem awardsWebWeberJ, SuQ, AntoniettiM, et al. Exploring polymers of intrinsic microporosity-microporous, soluble polyamide and polyimide [J]. Macromol. Rapid. Comm., 2007, 28: 1871 [7] SwaidanR J, GhanemB, SwaidanR, et al. Pure- and mixed-gas propylene/propane permeation properties of spiro- and triptycene-based microporous polyimides [J]. J. Membr. literary gathering crosswordWebWe report a molecular simulation study for gas permeation in two membranes constructed from polymers of intrinsic microporosity (PIM-1 and PIM-7). With rigid ladder polymer … literary generalizationWebApr 22, 2005 · This concept article describes recent research directed towards the synthesis of polymeric materials that possess microporosity that is intrinsic to their molecular … literarygenius shakespeareWebI am involved in organic synthesis, monomer & polymer design, the preparation and characterisation of novel Polymers of Intrinsic Microporosity (PIMs) both within the research group and also with commercial partners for scale up projects. I am entrusted by the PI to identify and solve problems in a timely… Show more literary genealogyWebPorphyrin-based polymers of intrinsic microporosity (PIMs) in photocatalytic degradation of a mustard-gas simulant (2-chloroethyl ethyl sulfide (2-CEES)) was demonstrated. Under … importance of specific presentation stylesWebSep 24, 2012 · Intrinsic microporosity in polymers is defined as “a continuous network of interconnected intermolecular voids, which forms as a direct consequence of the shape … literary genius meaning